Katherine Pierce (born Katerina Petrova) is a vampireand former lover of Damon and Stefan Salvatore. She isfirst shown in recurring flashbacks, depicting herphysically romantic relationship with the Salvatore brothers, eventually turning them, but was captured by the townspeople of Mystic Falls to be destroyed. However, behind her sweet nature, Katherine revealed her deceptive side and escaped her would-be death with the help of George Lockwood.
145 years later, Katherine returned to Mystic Falls and started toying with the Salvatores again, cutting off her loose ends by destroying tomb vampires. Katherine was deeply hated for the murder and the turning of Caroline Forbes into a vampire, and using a werewolf, Mason Lockwood, to retrieve the moonstone, an essential element to break the curse of the Sun and the Moon. Katherine is exposed as a Doppelganger who spent her immortal life fleeing an Original named Klaus, and although she chose Stefan over Damon, she promisedJohn Gilbert that she would help protect her descendantElena Gilbert, who is the center of the brothers' hearts.
She is recently portrayed as the main antagonist, but the arrival of Elijah, an Original vampire, diminishes her attitude and frightens her with the knowledge that Klaus would come after her. She was Klaus' prisoner for a while, but was released when Klaus ordered her to deliver the vial of Klaus' blood to Damon; her current whereabouts are unknown.
She is a member of the Petrov Family.
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